| Singles competition |
| 1. #2 Sara Daavettila (NC) vs. #49 Kelly Chen (DU) 6-1, 2-6, 4-3, unfinished |
| 2. #41 Alexa Graham (NC) vs. #19 Georgia Drummy (DU) 4-6, 7-6 (7-5), 3-0, unfinished |
| 3. #39 Chloe Beck (DU) def. #27 Cameron Morra (NC) 6-1, 6-4 |
| 4. #32 Makenna Jones (NC) def. #40 Meible Chi (DU) 0-6, 6-4, 6-4 |
| 5. #36 Fiona Crawley (NC) def. Margaryta Bilokin (DU) 6-1, 6-0 |
| 6. #117 Reilly Tran (NC) def. Karolina Berankova (DU) 5-7, 6-1, 6-1 |
| Doubles competition |
| 1. #10 Margaryta Bilokin/Meible Chi (DU) def. #2 Cameron Morra/Sara Daavettila (NC) 6-2 |
| 2. #4 Makenna Jones/Elizabeth Scotty (NC) def. #9 Chloe Beck/Karolina Berankova (DU) 6-4 |
| 3. #34 Alle Sanford/Reilly Tran (NC) def. #41 Kelly Chen/Georgia Drummy (DU) 7-5 |
| Match Notes |
| Duke 18-7; National ranking #18 |
| North Carolina 30-0; National ranking #1 |
| Order of finish: Doubles (2,1,3); Singles (5,3,6,4) |
| 2021 Division I NCAA Tournament - Quarterfinals |
| UNC - #1 National Seed |
| T-3:03 |